Academic Year: | 2019/0 |
Owning Department/School: | Department of Chemistry |
Credits: | 6 [equivalent to 12 CATS credits] |
Notional Study Hours: | 120 |
Level: | Intermediate (FHEQ level 5) |
Period: |
- Semester 2
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Assessment Summary:
| EX 100% |
Assessment Detail: | |
Supplementary Assessment: |
- Like-for-like reassessment (where allowed by programme regulations)
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Requisites: |
In taking this module you cannot take CH20151 OR take CH20152
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Description:
| Aims: Second half of year long unit: To introduce and expand on advanced physical chemistry methods in kinetics, spectroscopy, surfaces and quantum mechanics.
Learning Outcomes: After studying this Unit, students should be able to:
* Account in kinetic terms for the mechanism of reactions in liquids;
* Describe the effect of light on some chemical reactions and account for the rates of photochemical processes;
* Describe and define the types of adsorption at solid surfaces;
* Explain the qualitative and quantitative basis of catalysis and physical adsorption;
* Define surface tension and solve simple problems involving its application;
* Define and interpret the forces between two colloids.
Skills: Numeracy (F, A), Problem solving (T, F, A), Independent working (F).
Content: Theoretical treatments of reaction kinetics and examples of their application e.g. Reactions in solution. Diffusion and activation control, the "cage" effect.
Experimental methods for studying reactions:
Basic photochemical methods and processes. Applications of photochemistry. Kinetics of photochemical reactions.
Introduction to surfaces. chemisorption versus physisorption.
adsorbed amounts. Types of isotherms: Langmuir Isotherm. determination of heat of adsorption,BET isotherm: Introduction to heterogeneous catalysis. Kinetics of catalysis. Langmuir Hinshelwood mechanism. Eley Rideal mechanism. Catalysis examples Molecular basis and consequences of surface tension. Colloid stability. Micellisation. Gibbs equation.
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Programme availability: |
CH20179 is only available to visiting/exchange students
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